New Jobs:

- Sr Scientist (Ionis)

- Sr Scientist (AbbVie)

- Postdoc (Los Alamos)

- Research Chemist (Optima)

Latest Internships:

- USC

  (Summer 2018)

- Kansas State

  (Summer 2018)



Pd(PPh3)2Cl2

[Bis(triphenylphosphine)palladium(II) Dichloride]


Other Names:

Dichlorobis(triphenylphosphine)palladium(II)

Bis(triphenylphosphine)dichloropalladium(II)

Palladium(II)bis(triphenylphosphine) dichloride

trans-Dichlorobis(triphenylphosphine)palladium(II)



General Information:


Structure:



CAS Number: 13965-03-2

Molecular Weight: 701.90 g/mol

Appearance: Yellow solid


Pd(PPh3)2Cl2 is a catalyst commonly employed in palladium catalyzed reactions such as Suzuki reactions, Sonogashira reactions, Heck reactions, etc. Pd(PPh3)2Cl2 is generally more stable at room temperature and has a longer shelf-life than Pd(PPh3)4.




Common Uses:


Catalyst in Suzuki reactions





Catalyst in Sonogashira reactions





References:


1) WO2012149280, page 80

2) WO2010016005, page 86

3) Wikipedia: Bis(triphenylphosphine)palladium chloride (link)

4) www.sigmaaldrich.com: Bis(triphenylphosphine)palladium(II) dichloride (link)

5) www.alfa.com: 10491 trans-Dichloro(triphenylphosphine)palladium(II), Pd 14.0% min (link)

6) www.strem.com: trans-Dichloro(triphenylphosphine)palladium(II), 99% (99.9+%-Pd) (link)

7) Molander, G. A.; Handbook of Reagents for Organic Synthesis, Catalyst Components for Coupling Reactions