New Jobs:

- Sr Scientist (Ionis)

- Sr Scientist (AbbVie)

- Postdoc (Los Alamos)

- Research Chemist (Optima)

Latest Internships:

- USC

  (Summer 2018)

- Kansas State

  (Summer 2018)



Dppf

[1,1'-Bis(diphenylphosphino)ferrocene]


Other Names:

1,1'- Bis(diphenylphosphanyl) ferrocene

1,1'- Ferrocenediyl- bis(diphenylphosphine)





General Information:


Structure:



CAS Number: 12150-46-8

Molecular Weight: 554.38 g/mol

Melting Point: 181-183 C


1,1'-Bis(diphenylphosphino)ferrocene (Dppf) is a diphosphine ligand used in homogeneous catalysis. Dppf is commonly used in palladium-catalyzed coupling reactions, but also is used with a variety of other Group 9 and 10 transition metals such as rhodium and nickel.




Common Uses:


Ligand in palladium catalyzed reactions





References:


1) WO2010032200, page 132

2) Wikipedia: 1,1'-Bis(diphenylphosphino)ferrocene (link)

3) www.sigmaaldrich.com: DPPF (link)

4) www.alfa.com: B21166 1,1’-Bis(diphenylphosphino)ferrocene, 97% (link)

5) Molander, G. A.; Handbook of Reagents for Organic Synthesis, Catalyst Components for Coupling Reactions